全文获取类型
收费全文 | 35190篇 |
免费 | 6761篇 |
国内免费 | 5068篇 |
专业分类
化学 | 25791篇 |
晶体学 | 482篇 |
力学 | 2210篇 |
综合类 | 432篇 |
数学 | 4140篇 |
物理学 | 13964篇 |
出版年
2024年 | 36篇 |
2023年 | 688篇 |
2022年 | 900篇 |
2021年 | 1168篇 |
2020年 | 1554篇 |
2019年 | 1557篇 |
2018年 | 1332篇 |
2017年 | 1284篇 |
2016年 | 1750篇 |
2015年 | 1846篇 |
2014年 | 2180篇 |
2013年 | 2728篇 |
2012年 | 3326篇 |
2011年 | 3432篇 |
2010年 | 2415篇 |
2009年 | 2490篇 |
2008年 | 2672篇 |
2007年 | 2281篇 |
2006年 | 2143篇 |
2005年 | 1787篇 |
2004年 | 1432篇 |
2003年 | 1064篇 |
2002年 | 1049篇 |
2001年 | 881篇 |
2000年 | 676篇 |
1999年 | 637篇 |
1998年 | 494篇 |
1997年 | 501篇 |
1996年 | 423篇 |
1995年 | 385篇 |
1994年 | 333篇 |
1993年 | 274篇 |
1992年 | 200篇 |
1991年 | 208篇 |
1990年 | 168篇 |
1989年 | 117篇 |
1988年 | 116篇 |
1987年 | 98篇 |
1986年 | 75篇 |
1985年 | 63篇 |
1984年 | 45篇 |
1983年 | 46篇 |
1982年 | 33篇 |
1981年 | 27篇 |
1980年 | 22篇 |
1979年 | 14篇 |
1976年 | 7篇 |
1975年 | 13篇 |
1959年 | 6篇 |
1957年 | 6篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
21.
Jia Yang Xingang Li Wenjun Li Xin Xi Qian Du Feng Pan Songqing Liu 《Biomedical chromatography : BMC》2020,34(8):e4857
Because of its unpredictable side effects and efficacy, the anticancer drug docetaxel (DTX) requires improved characterisation of its pharmacokinetic profiles through population pharmacokinetic studies. A sensitive and rugged LC–MS/MS method for the detection of DTX in human plasma was developed and optimised using paclitaxel as an internal standard (IS). The plasma samples underwent rapid extraction using hybrid solid-phase extraction-protein precipitation. The analyte and IS were separated with an isocratic system on a Zorbax Eclipse Plus C18 column using water containing 0.05% acetic acid along with 20 μM of sodium acetate and methanol (30/70, v/v) as the mobile phase. Quantification was performed using a triple quadrupole mass spectrometer through multiple reaction monitoring in positive mode, using the m/z 830.3 → 548.8 and m/z 876.3 → 307.7 transitions for DTX and paclitaxel, respectively. The range of the calibration curve was 1–500 ng/mL for DTX, and the linear correlation coefficient was >0.99. The accuracies ranged from −4.6 to 4.2%, and the precision was no higher than 7.0% for the analytes. No significant matrix effect was observed. Both DTX and the IS showed considerable recovery. This method was finally applied to the establishment of a population pharmacokinetic model to optimise the clinical use of DTX. 相似文献
22.
Introducing plasmonic metals into semiconductor materials has been proven to be an attractive strategy for enhancing photocatalytic activity in the visible region. In this work, a novel and efficient Ag/Ag2WO4/g‐C3N4 (AACN) ternary plasmonic photocatalyst was successfully synthesized using a facile one‐step in situ hydrothermal method. The composition, structure, morphology and optical absorption properties of AACN were investigated using X‐ray diffraction, Fourier transform infrared spectroscopy, scanning electron microscopy, and UV–visible diffuse reflectance spectroscopy, respectively. Photocatalytic performance of AACN was evaluated via rhodamine B and tetracycline degradation. The results indicated that AACN had excellent photocatalytic performance for rhodamine B degradation with a rate constant of 0.0125 min?1, which was higher than those of Ag2WO4 and Ag/Ag2WO4. Characterization and photocatalytic tests showed that the strong coupling effect between the Ag/Ag2WO4 nanoparticles and the exfoliated ultrathin g‐C3N4 nanosheets was superior for visible‐light responsivity and reduced the recombination rate of photogenerated electrons and holes. A proposed mechanism is also discussed according to the band energy structure and the experimental results. 相似文献
23.
24.
In this paper, the existence and multiplicity of positive solutions is established for Schrödinger‐Poisson system of the form where 0 ∈ Ω is a smooth bounded domain in , , and λ > 0 is a real parameter. Combining with the variational method and Nehari manifold method, two positive solutions of the system are obtained. 相似文献
25.
Russian Journal of Coordination Chemistry - Two Mo(VI) clusters, (H2L)3[Mo7O12(μ2-O)8(μ3-O)4] · 3H2O (I) and (H2L)2[Mo8O14(μ2-O)6(μ3-O)4(μ5-O)2] · 4DMF (II),... 相似文献
26.
Feng Sheng Ni Ziqiu Feng Shanshan Zhang Zhihui Liu Shuguang Wang Runbai Hu Jiawei 《Journal of Radioanalytical and Nuclear Chemistry》2019,319(3):737-748
Journal of Radioanalytical and Nuclear Chemistry - In this study, the UiO-66/Fe3O4/GO composite was prepared by one step method for removal of cesium ions (Cs+) in water and exhibited excellent... 相似文献
27.
Jessica K. Su Zexin Jin Rui Zhang Gang Lu Peng Liu Yan Xia 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(49):17935-17940
Ring‐opening metathesis polymerization (ROMP) has become one of the most important living polymerizations. Cyclopropenes (CPEs) remain underexplored for ROMP. Described here is that the simple swap of 1‐methyl to 1‐phenyl on 1‐(benzoyloxymethyl)CPEs elicited strikingly different modes of reactivity, switching from living polymerization to either selective single‐addition or living alternating ROMP. The distinct reactivity stems from differences in steric repulsions at the Ru alkylidene after CPE ring opening. Possible olefin or oxygen chelation from ring‐opened CPE substituents was also observed to significantly affect the rate of propagation. These results demonstrate the versatility of CPEs as a new class of monomers for ROMP, provide mechanistic insights for designing new monomers with rare single‐addition reactivity, and generate a new functionalizable alternating copolymer scaffold with controlled molecular weight and low dispersity. 相似文献
28.
Fan Wang Zicheng Zuo Liang Li Kuo Li Feng He Zhongqing Jiang Yuliang Li 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(42):15152-15157
A two‐dimensional (2D) carbon nanofilm with uniform artificial nanopores is an ideal material to ultimately suppress the fuel permeation in the proton exchange membrane fuel cells. Graphdiyne has great mechanical strength, high dimensional stability, and controllable nanopores, and has good prospects to play this crucial role. It is found that graphdiyne nanofilm with amino groups and natural nanopores can be easily prepared with high integrity. The aminated graphdiyne has good compatibility with the Nafion matrix owing to the acid–base interaction between them. The excellent comprehensive properties of graphdiyne in selectivity, dimensional stability, and integrity effectively improve the power performance and stability of fuel cells at wide temperature. Our results can be developed into a universal method that can easily realize the selective separation of ions and small molecules, and open a new way for the emerging applications in green energy. 相似文献
29.
Fan‐Li Zhang Jun Yi Wei Peng Petar M. Radjenovic Hua Zhang Zhong‐Qun Tian Jian‐Feng Li 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(35):12261-12265
The fundamental understanding of the subtle interactions between molecules and plasmons is of great significance for the development of plasmon‐enhanced spectroscopy (PES) techniques with ultrahigh sensitivity. However, this information has been elusive due to the complex mechanisms and difficulty in reliably constructing and precisely controlling interactions in well‐defined plasmonic systems. Herein, the interactions in plasmonic nanocavities of film‐coupled metallic nanocubes (NCs) are investigated. Through engineering the spacer layer, molecule–plasmon interactions were precisely controlled and resolved within 2 nm. Efficient energy exchange interactions between the NCs and the surface within the 1–2 nm range are demonstrated. Additionally, optical dressed molecular excited states with a huge Lamb shift of ≈7 meV at the single‐molecule (SM) level were observed. This work provides a basis for understanding the underlying molecule–plasmon interaction, paving the way for fully manipulating light–matter interactions at the nanoscale. 相似文献
30.
Mengci He Prof. Hongyan Shi Peng Wang Prof. Xiudong Sun Prof. Bo Gao 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(70):16106-16113
Molybdenum carbide (Mo2C) is a promising noble-metal-free electrocatalyst for the hydrogen evolution reaction (HER), due to its structural and electronic merits, such as high conductivity, metallic band states and wide pH applicability. Here, a simple CVD process was developed for synthesis of a Mo2C on carbon cloth (Mo2C@CC) electrode with carbon cloth as carbon source and MoO3 as the Mo precursor. XRD, Raman, XPS and SEM results of Mo2C@CC with different amounts of MoO3 and growth temperatures suggested a two-step synthetic mechanism, and porous Mo2C nanostructures were obtained on carbon cloth with 50 mg MoO3 at 850 °C (Mo2C-850(50)). With the merits of unique porous nanostructures, a low overpotential of 72 mV at current density of 10 mA cm−2 and a small Tafel slope of 52.8 mV dec−1 was achieved for Mo2C-850(50) in 1.0 m KOH. The dual role of carbon cloth as electrode and carbon source resulted into intimate adhesion of Mo2C on carbon cloth, offering fast electron transfer at the interface. Cyclic voltammetry measurements for 5000 cycles revealed that Mo2C@CC had excellent electrochemical stability. This work provides a novel strategy for synthesizing Mo2C and other efficient carbide electrocatalysts for HER and other applications, such as supercapacitors and lithium-ion batteries. 相似文献